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Electrolysis of dilute sulfuric acid

Dilute sulfuric acid contains water. The ions present in this mixture are H+ and OH- (from the water) and H+ and SO42- from the sulfuric acid. The H+ ions are attracted to the cathode and the two negative ions are attracted to the anode but it is the OH- ion which loses electrons.

  • H+ ions are attracted to the cathode, gain electrons and form hydrogen gas
  • OH- ions are attracted to the anode, lose electrons and form oxygen gas and water

Higher tier

At the cathode: 2H+ + 2e- → H2

At the anode: 4OH- → O2 + 2H2O + 4e-

Colourless gases are produced at each electrode. The volume of hydrogen produced at the cathode is twice the volume of oxygen produced at the anode.